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From acyl boronates to functional boronate-substituted and boron-containing heterocycles: emerging methods and applications
Over the past decade, acyl boronates have emerged as versatile and valuable precursors in organic synthesis, facilitating ...
One-pot Dearomatizative C-Nucleophiles Telescoped Addition to Fluorinated 1,2,4-Oxadiazoles - Regioselective N-Functionalization
The constitutive low aromaticity of easily accessible 5-trifluoromethyl-1,2,4-oxadiazoles is explored for the editing modi...
Recent advances in earth-abundant transition-metal-catalysed asymmetric oxidative sp³-sp³ cross-couplings
Asymmetric sp³-sp³ cross-coupling reactions (including Csp³-Csp³, Csp³-Xsp3 and Xsp³-Xsp3 co...
Metal- and additive-free ipso-benzylation of arylsilanes to access diarylmethanes
A metal- and additive-free ipso-benzylation of arylsilanes was developed to efficiently synthesize symmetrical and unsymme...
Correction: Synthesis of quinoline derivatives by palladium-catalyzed isocyanide insertion/undirected C(sp2)–H functionalization/[4 + 1] cyclization reactions involving aryl isocyanide
Correction for ‘Synthesis of quinoline derivatives by palladium-catalyzed isocyanide insertion/undirected C(sp2)–H functio...
Biomimetic Total Synthesis of Ten Securinega Alkaloids
The Securinega alkaloids are a diverse family of polycyclic alkaloids with broad biological importance. In this study, a f...
Lewis acid-catalyzed cascade via intercepted Meyer-Schuster O-allenylation and [3,3]-sigmatropic rearrangement: Divergent synthesis of 2-alkenylanilines and indoles
A Lewis acid-catalyzed cascade reaction has been developed for the synthesis of 2-alkenylaniline derivatives bearing an en...
Carbonyls as Potential Alkenyl Carbanions for Deoxygenative Cross-Coupling with Alkyl Electrophiles
The example of carbonyls as alkenyl carbanions for deoxygenative cross-coupling with alkyl electrophiles has been develope...
Benzophenone-catalyzed alkenylative pyridylation of vinylarenes with alkenylboronic esters
We report a mild three-component reaction system combining styrenes, alkenylboronic esters, and 4-cyanopyridine for the ef...
Crab-shape C2-symmetric chiral Tpy-bisulidine ligands: design, synthesis and application in diversity-oriented asymmetric catalysis
Terpyridine-type ligands were renowned for their rich coordination with various metal ions. However, their high cost and t...
Outer-Sphere Reductive Elimination as the Enantio-Determining Step in Ir III /Ni II Metallaphotoredox-Catalyzed α-(Hetero)aryl Amination: A DFT Study
The Ir III /Ni II metallaphotoredox-catalyzed enantioselective cross-coupling of chiral α-(hetero)aryl amines was systemat...
Base-Promoted Synthesis of β-Keto Sulfone with N-Acyl Pyrroles and Allyl Sulfones
An efficient method has been developed for the direct transformation of allyl sulfone to β-keto sulfones by their reaction...
Visible-Light-Driven Electrophilic Chalcogen Species: Integration of Sustainable Synthesis, Green Metrics, and Computational Discovery of Antioxidants
The emergence of green chemistry principles has driven researchers to develop more sustainable methods for organic synthes...
Ligand-Controlled Switchable Nickel-Catalyzed Coupling of Nitriles with Aryl Triflates: Divergent Synthesis of Ketones and Diarylmethanes
A ligand-controlled switchable nickel-catalyzed coupling reaction between nitriles and aryl triflates has been developed, ...
Access to (E)-δ-Vinyl-Homoallylic Alcohols/Ethers/Pyrazoles by Ring-opening Nucleophilic Substitution of cyclopropyl allylic alcohols
A highly efficient Lewis acid-catalyzed ring-opening nucleophilic substitution of cyclopropyl allylic alcohols has been de...
Azlactone Rings: Uniting Tradition and Innovation in Synthesis
Azlactones, also known as oxazolones, are a class of heterocyclic compounds with significant relevance in the synthesis of...
1,2,3-Trifunctionalization of α,α-Disubstituted Vinyl Aldehydes Enabled by Radical 1,2-Migration of Formyl
As compared to the well-established 1,2-difunctionalizations, the 1,2,3-trifunctionalization of alkenes has been much less...
Cross-Dehydrogenative Radical Coupling Enabled by K₂S₂O₈: Efficient Synthesis of 2,3-Dicarbonyl Quinolines from Enaminones and Glycine Derivatives
Herein, we report a K₂S₂O₈-mediated metal-free radical dehydrogenative cross-coupling reaction that achieves direct C(sp&#...
Crucial Role of Palladium (0/II) Catalyst in the Synthesis of the Multi-Resonance Thermally Activated Delayed Fluorescence Emitters
Boron and nitrogen/oxygen-based multi-resonance thermally activated delayed fluorescence (MR-TADF) emitters represent cutt...
TFPN-Mediated Acyl Fluoride Platform: Efficient Synthesis of Esters, Thioesters, and Macrolactones from Carboxylic Acids with Diverse Nucleophiles
A TFPN (3,4,5,6-tetrafluorophthalonitrile)-mediated esterification strategy has been developed for the efficient synthesis...
NaH-Promoted One-Pot Oxidation/Aromatization and C-3H Chalcogenation of Indoline: Atmospheric Control-Based Selective Intermediates
A sub-stoichiometric sodium hydride promoted strategy with diselenides and disulphides, has been devised for the one-pot c...
Acrolein Triftosylhydrazone: A Versatile Vinylcarbene Reagent
We report the development of acrolein triftosylhydrazone (AHZ-Tfs), an operationally safe and user-friendly reagent servin...
Chemodivergent Temperature Controlled Switchable Iron Catalysed Annulation of o-vinylaniline with Isatin Derivatives
Chemo-divergent approach enables to achieve regioselective and site-divergent transformations of multiple products by chan...
An aerobic copper-catalyzed multi-component reaction strategy for N',N'-diaryl acylhydrazines synthesis: reactions and mechanism
A sequential multi-component reaction has been achieved via aerobic copper-catalyzed intermolecular C-N/C-O bonds cascade ...
Enantioselective synthesis of chiral BCPs
Bicyclo[1.1.1]pentanes (BCPs) have emerged as an interesting scaffold in drug design. This strained molecule can act as bi...
Metal-free photocatalytic homo- and cross dimerization of α-hydroxy ketones via dual C(sp3)-H functionalization: synthesis of 2,3-dihydroxy-1,4-butanediones
The dimerization reactions of α-hydroxy ketones in the α-carbon site have been realized by visible light photocatalysis in...
Electrochemistry multicomponent cascade annulation and functionalization reaction to enable C(sp3)-H trifluoromethylation
Herein, we describe a novel electrochemistry facilitated one-pot multicomponent cascade annulation and bi-functionalizatio...
Dithiocarbamate mediated thioamidation via C-C single bond cleavage of styrene: Study of the protocol on decarbonylative and decarboxylative thioamidations
Dithiocarbamate salts have been explored in a novel C-C thioamidation of styrene in presence of ammonium persulfate and mo...
Highly regio- and stereoselective bromochlorination and bromoazidation of 1,3-dienes
A substrate-induced strategy for the bromochlorination and bromoazidation of diverse 1,3-dienes has been reported. This pr...
Obscurinin A, a unique Lycopodium alkaloid possessing an 8/6/6/6/5 pentacyclic system isolated from Lycopodium obscurum L.
Obscurinin A (1), an unprecedented Lycopodium alkaloid featuring an 8/6/6/6/5 ring system, was isolated from the methanol ...
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